Objective: To identify low-density polyethyene(LDPE) eye drop bottles adulterated with other plastics and to study the differences between LDPE plastic pellets and recycled plastics. Methods: The melting point of LDPE eye drop bottles and plastic pellets of eight manufacturers were determined by differential scanning calorimetry(DSC). The melting curve, oxidation induction temperature(dynamic OIT) and oxidation induction time(isothermal OIT) in LDPE plastic pellets and recycled materials with different times(one, three and six) were obtained by DSC method. Results: DSC can not only identify LDPE materials,but also distinguish the LDPE plastic granules and recycled plastics. Conclusion: DSC analysis can provide the foundation of identifying material consistency in product and the raw materials.
[1] 孙璐,赵雄燕,孙占英,等.食品用塑料制品掺杂回收塑料鉴别技术的研究进展[J].塑料科技, 2013, 41(12):91 SUN L, ZHAO XY, SUN ZY, et al. Research progress in identification technologies for food-relatedplastic products doped with recycled plastics[J]. Plast Sci Technol,2013, 41(12):91
[2] 谢兰桂.再生塑料的识别研究[D].北京:北京协和医学院, 2011 XIE LG. Study on the Identification of Recycled Plastics[D]. Beijing:Peking Union Medical College,2011
[3] 金宏,王丹丹,陶巧凤.差示扫描量热法鉴别药用高密度聚乙烯瓶中掺杂聚丙烯[J].药物分析杂志,2012, 32(4):647 JIN H, WANG DD, TAO QF. Identification of high-density polyethylene bottle adulterated with polypropylene by DSC[J]. Chin J Pharm Anal,2012, 32(4):647
[4] GB/T 19466. 1-2004塑料差示扫描量热法第1部分:通则[S]. 2004 GB/T 19466. 1-2004 Plastics-Differential Scanning Calorimetry (DSC)-Part 1:General Principles[S]. 2004
[5] ISO 11357-1:1997 Plastics-Differential Scanning Calorimetry (DSC)-Part 1:General Principles[S]. 1997
[6] GB/T 19466. 3-2004塑料差示扫描量热法第3部分:熔融和结晶温度及热焓的测定[S]. 2004 GB/T 19466. 3-2004 Plastics-Differential Scanning Calorimetry (DSC)-Part 3:Determination of Temperature and Enthalpy of Melting and Crystallization[S]. 2004
[7] ISO 11357-3:1999 Plastics-Differential Scanning Calorimetry (DSC)-Part 3:Determination of Temperature and Enthalpy of Melting and Crystallization[S]. 1999
[8] GB/T 19466. 6-2009塑料差示扫描量热法第6部分:氧化诱导时间(等温OIT)和氧化诱导温度(动态OIT)[S]. 2009 GB/T 19466. 6-2009 Plastics-Differential Scanning Calorimetry (DSC)-Part 6:Determination of Oxidation Induction Time (Isothermal OIT)and Oxidation Induction Temperature(Dynamic OIT)[S]. 2009
[9] ISO 11357-6:2008 Plastics-Differential Scanning Calorimetry (DSC)-Part 6:Determination of Oxidation Induction Time (Isothermal OIT)and Oxidation Induction Temperature(dynamic OIT)[S]. 2008
[10] USP 38-NF 33. General Chapter<661>Containers-Plastics[S]. 2015
[11] 许都.最新塑料牌号性能用途速查手册[M].第三版.长春:吉林出版发行集团,2011:19 XU D. The New Plastic Quick Grade Performance Use Manual[M]. 3rd Ed. Changchun:Jilin Publishing and Distribution Group,2011:19
[12] YBB00062002低密度聚乙烯药用滴眼剂瓶[S]. 2002 YBB00062002 LDPE Bottles for Eye Drops[S]. 2002
[13] 李婷.聚乙烯化工材料的结构特点和应用发展[J].化学工业, 2014, 32(1):20 LI T. The structure characteristics of polyethylene chemical materials and application development[J]. Chem Ind,2014, 32(1):20
[14] 张立军,马子贵,姜进宪,等.塑料氧化诱导时间和氧化诱导温度的标准试验方法综述[J].橡胶技术与装备, 2009, 35(3):5 ZHANG LJ,MA ZG,JIANG JX,et al. The standard test methods of plastic oxidation induction time and oxidation induction temperature[J]. Chin Plast Technol Equip,2009,35(3):5
[15] 张立军,刘丽军,姜进宪,等.差示扫描量热法测定塑料的氧化诱导时间和氧化诱导温度[J].橡胶技术与装备, 2010, 36(6):12 ZHANG LJ, LIU LJ, JIANG JX, et al. Determination of plastic oxidation induction time and oxidation induction temperature by DSC[J]. Chin Plast Technol Equip,2010, 36(6):12